Hey Lizzie:
No, the capital sigma is not used exclusively for Riemann sums. It is used in Riemann sums, though, because you're adding up a bunch of rectangle areas.
It is used to indicate summation from some point, say n=1, to some other point, maybe infinity, maybe something finite.
For instance, let's say we wanted to add up all the numbers from 1 to 100:
we could write this as:
\(\displaystyle \sum_{n=0}^{100}n=1+2+3+4+....+100\)