This is how I finished the problem:
Now, let's write:
\(\displaystyle s=2R\cdot\dfrac{r}{2R} \arccos\left(\dfrac{r}{2R}\right)\)
Let:
\(\displaystyle u=\dfrac{r}{2R}\)
And we now have the arc-length as a function of one variable:
\(\displaystyle s(u)=2Ru\arccos(u)\) where \(\displaystyle 0\le u\le1\)
So, we set about finding the critical value:
\(\displaystyle s'(u)=2R\left(-\dfrac{u}{\sqrt{1-u^2}}+\arccos(u)\right)=0\)
This implies:
\(\displaystyle \dfrac{u}{\sqrt{1-u^2}}=\arccos(u)\)
This cannot be algebraically solved to get an exact value, so using a numeric root finding method, we obtain:
\(\displaystyle u\approx0.652184623909186793860487473\)
And so the radius in question is:
\(\displaystyle r\approx1.304369247818373587720974946R\)
Now, since:
\(\displaystyle s(0)=s(1)=0\), we know the critical value we found is at a maximum.
Here is a graph showing \(\displaystyle s\) as \(\displaystyle r\) varies from \(\displaystyle 0\) to \(\displaystyle 2R\), with the maximum we found.