Well, by the Binomial Theorem:
[imath](4n + 0)^5 = 4( \text{some number} ) + 0^5 \equiv 0 \text{ (mod 4)}[/imath]
[imath](4n + 1)^5 = 4( \text{some number} ) + 1^5 \equiv 1 \text{ (mod 4)}[/imath]
[imath](4n + 2)^5 = 4( \text{some number} ) + 2^5 \equiv 0 \text{ (mod 4)}[/imath]
[imath](4n + 3)^5 = 4( \text{some number} ) + 3^5 \equiv -1 \text{ (mod 4)}[/imath]
When we sum from [imath]1^5[/imath] to [imath]100^5[/imath] we are adding the same number of 1 (mod 4) terms and -1 (mod 4) terms, so they cancel.
Thus all the terms that could be not equal to 0 (mod 4) cancel. Thus the sum is equal to 0 (mod 4).
-Dan