First be very sure that the calculator is set to radian mode.
Then divide that answer by pi. You should get 1/3.
On the other hand, you really should memorize the so-called ‘special angles’:
\(\displaystyle \L 0,\,\frac{\pi }{6},\,\frac{\pi }{4},\,\frac{\pi }{3},\,\frac{\pi }{2},\,\pi.\)