It's a simple rearrangement of the terms in the equation. You were given the following:
a^2 - b^2 + 25 +10a
You'll agree that 25 is 5 squared, and 10 is 5 times 2, yes? So make those replacements:
a^2 - b^2 + 5^2 + (5*2)a
And because addition and subtraction are commutative (i.e. they can be done in any order without effecting the answer), you can rearrange the terms:
a^2 + (5*2)a + 5^2 - b^2
Now you've got a quadratic in a. So, as Subhotosh Khan said, "Continue..."